Funct. Mater. 2017; 24 (3): 393-399.
GdVO4:Eu3+ nanoparticles - embedded CaCO3 microspheres: synthesis and characterization
1Institute for Scintillation Materials, STC "Institute for Single Crystals", National Academy of Sciences of Ukraine, 60 Nauky Ave., 61072 Kharkiv, Ukraine
2Institute for Single Crystals, STC "Institute for Single Crystals",National Academy of Sciences of Ukraine, 60 Nauky Ave., 61072 Kharkiv, Ukraine
In present study, we report on synthesis of fluorescent GdVO4:Eu3+ nanoparticle-embedded CaCO3 microparticles (CaCO3@GdVO4:Eu3+) and their characterization. Synthesized CaCO3@GdVO4:Eu3+ microspheres are of vaterite polymorph and about 2 <$E mu>m diameter with -12.80±0.82 mV zeta potential. The specific surface area of the CaCO3@GdVO4:Eu3+ microspheres and pore size distribution were analyzed by Brunauer-Emmett-Teller method. The microparticles was classified as macroporous ones with a wide distribution of pore sizes.The specific surface area for CaCO3@GdVO4:Eu3+ microspheres (SBET = 25.2 m2/g) is higher than reported for CaCO3 microparticles obtained without any additives. CaCO3@GdVO4:Eu3+ microspheres exhibit strong fluorescence both in a water solution and under fluorescent microscopy conditions that makes them attractive for bio-related application.
1. D.Liu, F.Yang, F.Xiong et al., Theranostics, 6, 1306 (2016). https://doi.org/10.7150/thno.14858
2. K.Kim, D.Pack, BioMEMS Biomed Nanotechn, 1, 19 (2015).
3. J.Panyam, V.Labhasetwar, Adv. Drug Delivery Rev., 55, 329 (2003). https://doi.org/10.1016/S0169-409X(02)00228-4
4. N.P.Omorphos, L.Kahn, D.M.Kalaskar, Colloids and Surf. B: Biointerfaces, 136, 440 (2015).
5. P.Newman, A.Minett, R.Ellis-Behnke et al., Nanomedicine, 9, 1139 (2013). 1 https://doi.org/10.1016/j.nano.2013.06.001
6. H.M.Hertz, J.C.Larsson, U.Lundstrom et al., Opt. Lett., 39, 2790 (2014). https://doi.org/10.1364/OL.39.002790
7. C.Sun, J.S.H. Lee, M.Zhang, Adv. Drug Delivery Rev., 60, 1252 (2008). https://doi.org/10.1016/j.addr.2008.03.018
8. L.Zhang, F.X.Gu, J.M.Chan et al., Clinical Pharmacology & Therapeutics, 83, 761 (2008). https://doi.org/10.1038/sj.clpt.6100400
9. A.Zaccaria, A.Bouamrani, L.Selek et al., ACS Chem. Neurosci., 4, 385 (2013). https://doi.org/10.1021/cn300116g
10. J.B.Wolinsky, Y.L.Colson, M.W.Grinstaff, J. Control. Release, 159, 14 (2012). https://doi.org/10.1016/j.jconrel.2011.11.031
11. W.Qin, K.Li, G.Feng et al., Adv. Funct. Mater., 24, 635 (2014). https://doi.org/10.1002/adfm.201302114
12. C.-L.Sun, T.Li, J.-Q.Jiang et al., J. Mater. Chem. B, 4, 7226 (2016). h https://doi.org/10.1039/C6TB01782G
13. N.Butoescu, Ch.A.Seemayer, G.Palmer et al., Arthritis Research & Theraphy, 11, R72 (2009). 1
14. S.Haruta, T.Hanafusa, H.Fukase et al., DiabetesTech. Ther., 5, 1 (2003). https://doi.org/10.1089/152091503763816409
15. M.Higaki, M.Kameyama, M.Udagawa et al., Diabetes Tech. Ther., 8, 369 (2006). https://doi.org/10.1089/dia.2006.8.369
16. W.Yang, D.Trau, R.Renneberg et al., J. Coll. Interface Sci., 234, 356 (2001). https://doi.org/10.1006/jcis.2000.7325
17. T.Patino, J.Soriano, L.Barrios et al., Sci. Rep., 5, 11371 (2015). https://doi.org/10.1038/srep11371
18. J.Wang, H.Cui, Theranostics, 6, 1274 (2016). https://doi.org/10.7150/thno.16479
19. Y.Geng, P.Dalhaimer, S.Cai et al., Nat. Nanotechnol., 2, 249 (2007). https://doi.org/10.1038/nnano.2007.70
20. K.Y.Win, E.Ye, C.P.Teng et al., Adv. Healthcare Mater., 2, 1571 (2013). https://doi.org/10.1002/adhm.201300077
21. M.Behra, N.Azzouz, S.Schmidt et al., Biomacromolecules, 14, 1927 (2013). https://doi.org/10.1021/bm400301v
22. D.Volodkin, Adv. Colloid Interf. Sci., 207, 306 (2014). https://doi.org/10.1016/j.cis.2014.04.001
23. D.B.Trushina, T.V.Bukreeva, M.V.Kovalchuk et al., Mater. Sci. Engin. C, 45, 644 (2014). https://doi.org/10.1016/j.msec.2014.04.050
24. Y.Boyjoo, V.K.Pareek, J.Liu, J. Mat. Chem. A, 2, 14270 (2014). https://doi.org/10.1039/C4TA02070G
25. Y.Ueno, H.Futagawa, Y.Takagi et al., J. Control. Release, 103, 93 (2005). https://doi.org/10.1016/j.jconrel.2004.11.015
26. D.V.Volodkin, N.I.Larionova, G.B.Sukhorukov, Biomacromolecules, 5, 1962 (2004). https://doi.org/10.1021/bm049669e
27. C.Peng, Q.Zhao, C.Gao, Colloid Surface A, 353, 132 (2010). https://doi.org/10.1016/j.colsurfa.2009.11.004
28. C.Wang, C.He, Z.Tong et al., Int. J. Pharm., 308, 160 (2006). https://doi.org/10.1016/j.ijpharm.2005.11.004
29. S.Haruta, T.Hanafusa, H.Fukase et al., DiabetesTech. Ther., 5, 1 (2003). https://doi.org/10.1089/152091503763816409
30. M.Higaki, M.Kameyama, M.Udagawa et al., DiabetesTech. Ther., 8, 369 (2006). https://doi.org/10.1089/dia.2006.8.369
31. J.Wang, J.-S.Chen, J.-Y.Zong et al., J. Phys. Chem. C, 114, 18940 (2010). https://doi.org/10.1021/jp105906p
32. C.Bouzigues, T.Gacoin, A.Alexandrou, Acs Nano, 11, 8488 (2011). https://doi.org/10.1021/nn202378b
33. J.Shen, L.-D.Sun, C.-H.Yan, Dalton. Trans., 14, 5687 (2008). https://doi.org/10.1039/b805306e
34. V.K.Klochkov, A.I.Malyshenko, O.O.Sedyh et al., Functional Materials, 1, 111 (2011).
35. B.C.Chakoumakos, M.M.Abraham, L.A.Boatner, J. Solid State Chem., 109, 197 (1994). https://doi.org/10.1006/jssc.1994.1091
36. J.A.Baglio, G.Gashurov, Acta Cryst. B, 24, 292(1968). https://doi.org/10.1107/S0567740868002189
37. C.Hsu, R.C.Powell, J. Luminescence, 10, 273 (1975). h https://doi.org/10.1016/0022-2313(75)90051-4
38. A.Huignard, V.Buissette, A.C.Franville et al., J. Phys. Chem. B, 107, 6754 (2003). h https://doi.org/10.1021/jp0342226
39. S.Ouhenia, D.Chateigner, M.A.Belkhir et al., J. Cryst. Growth, 310, 2832 (2008). https://doi.org/10.1016/j.jcrysgro.2008.02.006
40. N.A.N.Hanafy, M.L.De Giorgi, C.Nobile et al., J. Basic Appl. Sci., 4, 60 (2015).
41. F.A.Andersen, L.Brecevic, Acta Chem. Scand., 45, 1018 (1991). https://doi.org/10.3891/acta.chem.scand.45-1018
42. J.Chen, L.Xiang, Powder Technol., 189, 64 (2009). https://doi.org/10.1016/j.powtec.2008.06.004
43. H.Nebel, M.Neumann, C.Mayer, Matthias Epple, Inorg. Chem., 47, 7874 (2008). https://doi.org/10.1021/ic8007409
44. C.Du, J.Shi, L.Zhang et al., Mater. Sci. Eng. C, 33, 3745 (2013). https://doi.org/10.1016/j.msec.2013.05.004
45. A.Bragaru, M.Kusko, A.Radoi, Cent. Eur. J. Chem., 11, 205 (2013).
46. J.Tang, A.P.Alivistatos, Nano Lett., 6, 2701 (2006). https://doi.org/10.1021/nl0615930
47. D.K.Kanchan, H.R.Panchal, Turk. J. Phys., 22, 989 (1998).
48. D.Lin-Vien, N.Colthup, W.Fateley et al., The Handbook of IR and Raman Characteristic Frequencies of Organic Molecules, Academic Press, New York (1991).
49. J.B.Condon, Surface Area and Porosity Determinations by Physisorption: Measurement and Theory, Elsevier, Amsterdam (2006).
50. S.J.Cregg, K.S.W.Sing, Adsorption, Surface Area and Porosity, Academic Press, London, New York (1967)