Funct. Mater. 2018; 25 (3): 613-618.

doi:https://doi.org/10.15407/fm25.03.613

Quartz ceramics modified by nanodispersed silica additive

E.S.Khomenko, A.V.Zaichuk, E.V.Karasik, A.A.Kunitsa

State Higher Educational Establishment Ukrainian State University of Chemical Engineering, 8 Haharin Ave., 49005 Dnipro, Ukraine

Abstract: 

The article considers one of the ways to improve physical and technical characteristics of Quartz Ceramics. The method consists in adding the sintering activator into the quartz ceramic composition, i.e. Nanodispersed Silicon Dioxide obtained by means of sol-gel method based on Ethyl Silicate or Tetraethoxysilane. The amount of the additive amounts to 10 wt.%. Samples containing the activator absorb water 40-45 % less than the samples without activator, while the mechanical strength is increasing by 1.2-1.3 times. Moreover, this activator prevents the formation of Cristobalite phase being undesirable in the Quartz Ceramics.

Keywords: 
Quartz Ceramics, slurry, Ethyl Silicate, sol-gel, calcination, Cristobalite, firing, water absorption ability, mechanical performance.
References: 

1. Ye.I.Suzdaltsev, J. Refract. Techn. Ceram., 7-8, 21 (2009).

2. Yu.Ye.Pyvynskyi, Ye.I.Suzdaltsev, Quartz Ceramics and Refractories: Materials, their Properties and Application, Teploenerhetyk, Moscow (2008) [in Russian].

3. D.W.Richerson, Modern Ceramic Engineering: Properties, Processing, and Use in Design, CRC Press Taylor and Francis Group, Boca Raton (2006).

4. O.V.Zaichuk, O.A.Amelina, Zh. Voprosy Khimii i Khimicheskoi Tekhnologii, 6, 63 (2017).

5. RU Patent 2515737 (2014).

6. RU Patent 2263090 (2005).

7. RU Patent 2436206 (2011).

8. H.D.Semchenko, I.Yu.Shutieieva, A.N.Butenko et al., Sol-gel Composition for Polyfunctional Application, Raduha, Kharkov (2011) .

9. H.D.Semchenko, Sol-gel Process in Ceramic Technology, Kharkov (1997) [in Russian].

10. RU Patent 2436206 (2011).

11. RU Patent 2368576 (2009).

12. N.S.Savchenko, Synthesis and Study of the Properties of Structural and Functional Materials based on Silicon Oxide, Siberian Federal University, Tomsk (2008) [in Russian].

13. Ya.I.Huzman, Workshop on Ceramics Technology, Building Materials, Moscow (2005) [in Russian].

14. O.P.Ryzhova, O.S.Mikhailyuta, O.O.Sihunov, Methods for Studying the Silicates Structure, Ukrainian State University of Chemical Engineering, Dnepropetrovsk (2012).

15. L.S.Zevin, G.Kimmel, Quantitative X-Ray Diffractometry, Springer-Verlag New York, Inc., New York (1995). https://doi.org/10.1007/978-1-4613-9535-5

16. N.A.Shabanova, P.D.Sarkisov, Sol-gel Method. Nanodisperse Silica, BINOM. Laboratory of Knowledge, Moscow (2012) [in Russian].

17. N.A.Shabanova, P.D.Sarkisov, Fundamentals of Sol-gel Method of Nanodispersed Silica, Academic Book, Moscow (2004) [in Russian].

18. V.V.Potapov, A.N.Kashutin, A.A.Serdan et al., J. Nanoindustry, 2, 44 (2012).

19. A.F.Shymanskyi, O.I.Podkopaiev, M.N.Vasylieva et al., J. Siberian Federal University. Chemistry, 2, 307 (2009).

20. E.S.Khomenko, E.V.Karasik, V.I.Goleus, Functional Materials, 24, 593 (2017).

https://doi.org/10.15407/fm24.04.593

Current number: