Funct. Mater. 2019; 26 (2): 319-324.
Low-temperature viscoelastic relaxation in PMA polyimide (Kapton)
B.Verkin Institute for Low Temperature Physics and Engineering, National Academy of Sciences of Ukraine, 47 Nauky Ave., 61103 Kharkiv, Ukraine
In the temperature range 4.2-350 K for the first time was studied the temperature dependence of the dynamic Young's modulus and acoustic absorption of the polyimide film PMA (Kapton). Two low-temperature relaxation processes on the temperature dependences of the acoustic properties of the PMDA/ODA polyimide are recorded: <$E delta>-relaxation at 45 K and β-relaxation at 185 K. A microscopic interpretation of the mechanisms is responsible for the occurrence of <$E delta> and β relaxation in the PMDA/ODA polyimide is proposed. Estimates of the activation energy for these relaxation processes are obtained: δ-relaxation - 0.05 eV, β-relaxation - 0.7 eV.
1. N.A.Andronova, M.I.Bessonov, L.A.Laus, A.P.Rudakov, Polyimides: A New Class of Thermally Stable Polymers, Nauka, Leningrad (1968) [in Russian].
2. K.L.Mittal, Polyimides and Other High-Temperature Polymers: Synthesis, Characterization and Applications. Leiden, Boston (2009). https://doi.org/10.1163/ej.9789004170803.i-424
3. A.A.Askadskij, Struktura i Svojstva Teplostojkih Polimerov, Himija, Moscow (1981) [in Russian].
4. S.V.Vinogradova, V.A.Vasnev, Polycondensation Processes and Polymers, Nauka, Moscow (2000) [in Russian].
5. A.N.Krasovskii, N.P.Antonov, M.M.Koton et al., Polymer Sci., 21, 1038 (1979). https://doi.org/10.1016/0032-3950(79)90211-9
6. M.Kotera, T.Nishino, K.Nakamae, Polymer, 41, 3615 (2000). https://doi.org/10.1016/S0032-3861(99)00546-7
7. A.P.Rudakov, M.I.Bessonov, M.M.Koton et al., Doklady Akademii Nauk SSSR, 161, 617 (1965).
8. V.P.Soldatov, G.I.Kirichenko, V.V.Abraimov et al., Low Temp. Phys., 42, 817 (2016). https://doi.org/10.1063/1.4963917
9. Yu.A.Semerenko, G.I.Kirichenko, V.P.Soldatov, in: Abstr. Int. Conf. DFMN-2013, Moscow (2013), p.615.
10. Yu.A.Semerenko, G.I.Kirichenko, V.P.Soldatov, in: Abstr. Int. Conf. Physical Phenomena in Solids 2015, Kharkiv (2015), p.102.
11. A.Mitrofanov, P.Apel, I.Blonskaja, O.Orelovich, Tech. Phys., 76, 121 (2006).
12. I.V.Gofman, I.V.Abalov, V.E.Yudin, V.G.Tiranov, Phys.Solid State, 53, 1509 (2011). https://doi.org/10.1134/S1063783411070134
13. C.E.Sroog, A.L.Endrey, C.V.Abramo et al., J. Polym. Sci., A3, 1373 (1965). https://doi.org/10.1002/pol.1965.100030410
14. I.S.Braude, N.N.Galtsov, V.G.Geidarov et al., Low Temp. Phys., 43, 1226 (2017). https://doi.org/10.1063/1.5008418
15. Liliana Burakowski Nohara, Michelle Leali Costa, Mauro Angelo Alves et al., Mat. Res., 13, 245 (2010). https://doi.org/10.1590/S1516-14392010000200020
16. Jong-Hun Park, Ji-Hwan Lee, Aloysius Soon, Phys. Chem. Chem. Phys., 18, 21893 (2016). https://doi.org/10.1039/C6CP03249D
17. Liquid-Crystalline Order in Polymers, ed. by A.Blyumshtein, Nauka, Moscow (1981) [in Russian].
18. Modern Methods for Polymer Characterization, ed. by G.L.Slonimsky, Khimiya, Moscow (1982) [in Russian].
19. M.Hasegawa, S.Horii, Polymer J., 39, 610 (2007). https://doi.org/10.1295/polymj.PJ2006234
20. P.M.Morse, Vibration and Sound, McGraw-Hill, New York (1948).
21. H.M.Simpson, A.Sosin, Rev. Sci. Instrum., 48, 1392 (1977). https://doi.org/10.1063/1.1134903
22. V.D.Natsik, Yu.A.Semerenko, Low Temp. Phys., 45, 551 (2019). https://doi.org/10.1063/1.5097366
23. R.E.Barker, J. Appl. Phys., 38, 4234 (1967). https://doi.org/10.1063/1.1709110
24. Yu.A.Semerenko, Pribory. Tekhn. Eksper. 48, 162 (2005). https://doi.org/10.1007/s10786-005-0107-x
25. Yu.A.Semerenko, Instr. Exper. Techn., 48, 608 (2005). https://doi.org/10.1007/s10786-005-0107-x
26. M.V.Zinov'ev, V.A.Koval', L.I.Danilenko, V.P.Soldatov, Strength Mater, 6, 598 (1972).
27. I.I.Perepechko, Acoustic Methods of Investigating Polymers, Khimiya, Moscow (1973) [in Russian].
28. M.Baccaredda, Chim. Ind., 44, 1383 (1962).
29. E.A.Friedman, A.J.Ritger, R.D.Andrews, J. Appl. Phys., 40, 4243 (1969). https://doi.org/10.1063/1.1657182
30. I.I.Perepechko, Low-Temperature Properties of Polymers, Khimiya, Moscow (1977)
31. F.P.Reding, J. Polymer Sci., 21, 547 (1969). https://doi.org/10.1002/pol.1956.120219919
32. J.A.Sauer, R.G.Saba, J. Macromol. Sci.-Chem., A3, 1217 (1969). https://doi.org/10.1080/10601326908051825
33. P.D.Golub', I.I.Perepechko, Akusticheskij Zhurnal, 20, 38 (1974).
34. Y.S.Papir, E.Baer, J. Appl. Phys., 42, 4667 (1971). https://doi.org/10.1063/1.1659837
35. V.E.Smirnova, I.V.Gofman, V.K.Lavrent'ev, V.P.Sklizkova, Polymer Sci., A49, 1114 (2007). https://doi.org/10.1134/S0965545X07100082
36. S.P.Papkov, A.T.Kalashnik, Polymer Sci., A26, 2505 (1984). https://doi.org/10.1016/0032-3950(84)90204-1
37. Y.S.Papir, E.Baer, Mater. Sci. Eng., 8, 310 (1971). https://doi.org/10.1016/0025-5416(71)90098-X
38. K.Miki et al., Japan J. Appl. Phys., 5, 818 (1971). https://doi.org/10.1143/JJAP.5.818
39. D.H.Reneker, J. Polymer Sci.. 59, S39 (1962). https://doi.org/10.1002/pol.1962.1205916831
40. E.S.Ciark, in: Cryogenic Properties of Polymers. ed. by T.T.Seratini and J.L.Koening, Marcel Dekker, New York (1967).
41. W.Pechhold, Koll-Z. Bd., 228, S1 (1968). https://doi.org/10.1007/BF02125760
42. P.de Santis et al., J. Polymer Sci., A1, 1383 (1963). https://doi.org/10.1002/pol.1963.100010426
43. R.G.Brown, J. Chem. Phys., 40, 2900 (1964). https://doi.org/10.1063/1.1724924
44. J.L.Koenig, F.J.Boerio, J. Chem. Phys., 52, 4170 (1970). https://doi.org/10.1063/1.1673627
45. A.S.Nowick, B.S.Berry, Anelastic Relaxation in Crystalline Solids, Academic, New York (1972).
46. V.S.Postnikov, Internal Friction in Metals and Alloys, Springer, New York (1967). https://doi.org/10.1007/978-1-4899-4725-3
47. V.D.Natsik, Yu.A.Semerenko, Low Temp. Phys., 42, 138 (2016). https://doi.org/10.1063/1.4942907