Funct. Mater. 2019; 26 (3): 548-555.

doi:https://doi.org/10.15407/fm26.03.548

Physical-mechanical properties and structural-phase state of nanostructured wear-resistant coatings based on nitrides of refractory metals Ti and Zr

T.P.Hovorun1, O.V.Pylypenko1, K.V.Berladir1, K.O.Dyadyura1, M.N.Dunaeva1, S.I.Vorobiov2, A.Panda3

1Sumy State University, 2 Rymskogo-Korsakova Str., 40007 Sumy, Ukraine
2Institute of Physics, P.J.Safarik University in Kosice, 2 Srobarova Str., 04154 Kosice, Slovakia
3Technical University of Kosice, 1 Bayerova Str., 08001 Presov, Slovakia

Abstract: 

The physical and mechanical properties of coatings based on nitrides of refractory metals, their structure, phase composition and surface morphology depending on the parameters of condensation were analyzed. The peculiarities of the structure and behavior of nanostructural coatings based on nitrides of Ti and Zr refractory metals in multilayer TiN/ZrN coatings depending on the period of layered structure (size of nano grains, texture and emerging stresses) were established.

Keywords: 
multilayered TiN/ZrN coatings, structure of surface layers, nanocomposite coatings, hardness.
References: 

1. A.D.Pogrebnjak, O.M.Ivasishin, V.M.Beresnev, Usp. Fiz. Met., 17, 1 (2016). https://doi.org/10.15407/ufm.17.01.001

2. K.O.Dyadyura, T.P.Hovorun, O.V.Pylypenko et al., in: 2017 IEEE 7th Intern. Conf. Nanomaterials: Application & Properties (NAP), Odessa, Ukraine (2017), p.01FNC10-1.

3. M.Samuelsson, D.Lundin, J.Jensen et al., Surf. Coat. Technol., 202, 591 (2010). https://doi.org/10.1016/j.surfcoat.2010.07.041

4. T.P.Hovorun, O.A.Bilous, O.P.Gaponova et al., Ukr. J. Phys., 62, 132 (2017). https://doi.org/10.15407/ujpe62.02.0132

5. F.Magnus, A.S.Ingason, O.B.Sveinsson et al., Thin Solid Films, 520, 1621 (2011). https://doi.org/10.1016/j.tsf.2011.07.041

6. T.P.Hovorun, O.V.Pylypenko, M.V.Hovorun, K.O.Dyadyura, J. Nano- Electron. Phys., 9, 02026(7pp) (2017). https://doi.org/10.21272/jnep.9(2).02026

7. A.A.Vereshchaka, A.S.Vereshchaka, O.Mgaloblishvili et al., Int. J. Adv. Manuf. Technol., 72, 303 (2014). https://doi.org/10.1007/s00170-014-5673-2

8. A.Anders, J. Phys. Appl. Phys., 40, 2272 (2007). https://doi.org/10.1088/0022-3727/40/8/S06

9. B.B.Straumal, N.F.Vershinin, A.A.Asrian et al., Mater. Phys. Mech., 5, 39 (2002).

10. H.C.Barshilia, S.Acharya, M.Ghosh, Vacuum, 85, 411 (2010). https://doi.org/10.1016/j.vacuum.2010.08.003

11. Ye.K.Sevidova, Yu.G.Gutsalenko, N.V.Kryukova, Elektronnaya Obrabotka Materialov, 50, 92 (2014).

12. A.Kovalev, D.Wainstein, A.Rashkovskiy, Surf. Interface Anal., 42, 1361 (2010). https://doi.org/10.1002/sia.3290

13. R.Gago, F.Soldera, R.Hubner et al., J. Alloys Comp., 561, 87 (2013). https://doi.org/10.1016/j.jallcom.2013.01.130

14. Q.Meng, M.Wen, P.Liu et al., Mater. Lett., 94, 61 (2013). https://doi.org/10.1016/j.matlet.2012.12.011

15. G.Gassner, Ph.Mayrhofer, K.Kutschey et al., Surf. Coat. Technol., 201, 3335 (2006). https://doi.org/10.1016/j.surfcoat.2006.07.067

16. T.N.Koltunowicz, P.Zhukowski, V.Bondariev et al., J. Alloys Compd., 615, S361 (2014). https://doi.org/10.1016/j.jallcom.2013.12.125

17. G.Abadias, A.Michel, C.Tromas et al., Surf. Coat. Technol., 202, 844 (2007). https://doi.org/10.1016/j.surfcoat.2007.05.068

18. S.-F.Chen, Y.-C.Kuo, C.-J.Wang et al., Surf. Coat. Technol., 231, 247 (2013). https://doi.org/10.1016/j.surfcoat.2012.03.002

19. J.Musil, P.Novak, M.Hromadka et al., Surf. Coat. Technol., 215, 386 (2013). https://doi.org/10.1016/j.surfcoat.2012.06.090

20. I.N.Martev, D.A.Dechev, N.P.Ivano et al., J. Phys. Conf. Ser., 223, 012 (2010). https://doi.org/10.1088/1742-6596/223/1/012019

21. A.P.Shpak, V.P.Mayboroda, Yu.A.Kunitskiy et al., Nanosloistye Kompozitsionnye Materialy i Pokrytiya, Kyiv, Akademperiodika (2004), p.164.

22. Ye.Sheynman, Metallovedeniye i Termicheskaya Obrabotka Metallov, 12, 41 (2008).

23. K.R.Kazdaev, R.B.Abylkalykova, L.I.Kveglis, J. Sib. Fed. Univ. Eng. Technol., 5, 560 (2012).

24. H.W.Yen, C.Y.Huang, J.R.Yang, Scr. Mater., 61, 616 (2009). https://doi.org/10.1016/j.scriptamat.2009.05.036

25. D.Machon, D.Daisenberger, E.Soignard et al., Phys. Stat. Solid. A, 203, 831 (2006). https://doi.org/10.1002/pssa.200521008

26. G.Zhang, F.Tianxiang, W.Tao, C.Hailin, Appl. Surf. Sci., 274, 231 (2013). https://doi.org/10.1016/j.apsusc.2013.03.021

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