Funct. Mater. 2025; 32 (1): 13-20.
doi:https://doi.org/10.15407/fm32.01.13
Thermal stability of perovskites CH3NH3PbX3 (X = Cl, Br, I)
G.V. Kurdyumov Institute for Metal Physics of the National Academy of Sciences of Ukraine, blvd. Academician Vernadsky, 36, 03142 Kyiv, Ukraine
Abstract:
The morphology and structures of perovskites were investigated using scanning electron microscopy and X-ray diffraction methods. The samples exhibit a monophase structure. The thermal stability and degradation processes of a series of perovskites CH3NH3PbX3 (where X = Cl, Br, I) were analyzed by the thermogravimetric method. The results indicate that the thermal stability is preserved up to 335°C for X = Cl, 330°C for X = Br, and 310°C for X = I. Additionally, a correlation was established between the thermal stability of CH3NH3PbX3 perovskites and the characteristics of the halogen atom in their structure. It was concluded that the thermal stability of hybrid organic-inorganic perovskites can be adjusted by varying the halogen atom incorporated in the perovskite structure.
Keywords:
perovskite, thermal stability, degradation of perovskites, structural transformations.
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